The Defence Science and Technology Laboratory confirmed the victims were exposed to Novichok.
Chief Constable Kier Pritchard said he "fully supports" the decisions taken by officers, who thought initially the couple had fallen ill after taking illegal drugs.
Novichok remains highly toxic for a considerable period of time, so even the tiniest trace remaining in a container picked up by the victims could account for their severe illness.
In a blistering attack in the Commons, Javid demanded that the Kremlin provide an explanation for the two episodes.
"It is completely unacceptable for our people to be either deliberate or accidental targets, or for our streets, our parks, our towns, to be dumping grounds for poison."
A Russian Embassy spokesman said: "It is regrettable that UK officials try to link a second poisoning with Russia without having produced any credible results of the investigation of the first one.
"Instead of genuine co-operation, London is doing everything possible to muddy the waters, to confuse and frighten its own citizens. One can only guess what the reasons behind such a line of behaviour are."
Officers were called to a home in Muggleton Rd, Amesbury, when Sturgess collapsed. They were called back later that day when Rowley also fell ill.
Six sites visited by Rowley and Sturgess before they fell ill were cordoned off.
Skripal and his daughter have since left hospital.