"The boy was treated at the scene be NSW Ambulance paramedics for suspected head injuries," she said. He was in a serious condition at the time.
CareFlight said the boy is in a critical condition and was flown to the Sydney Children's Hospital at Randwick.
The Daily Telegraph reports an update was sent from the school to parents at midday on Monday advising "there has been an accident at school involving one child" and the student's parents had been notified.
Monday marked the first day of a "phased return" to school in the third week of term two during the coronavirus crisis.
"Most students will continue learning from home and will only attend school one day each week," a NSW Department of Education statement, shared on the primary school's website on Friday, reads.
The department has been contacted for further information about Monday's incident.