Venus and Puetz started superbly and after the Kiwi held they broke Herbert first service game of the match.
Great returning helped Puetz and Venus to a 3-0 advantage in only eight minutes. Puetz served out the first set with three consecutive smashes.
The second set was extremely tight with the French pair both managing to save break points early in the set while Venus and Puetz saved deciding points at 2-3 and 3-4 respectively. The German dug deep to save four set points at 5-6 to send the set into a tie break with the French pair won when a low backhand return winner from Mahut forced Venus into an error.
It was an epic match tie break to decide the outcome with Mahut and Herbert taking an early 5-2 lead but Venus and Puetz fought back and led 8-7 when Venus hit a stinging return of serve enabling Puetz to put away an easy volley. The Kiwi brought up a first match point at 9-7 with a huge first serve but then served a double fault to let Herbert and Mahut back in it.
Hugues-Herbert saved a second Championship point with a first service winner but a delightful lob from Puetz found the line to bring up a third match point and Puetz closed the match out with a nice serve allowing Venus to put away the volley for a memorable win.
While Venus and Puetz won't be at the ATP Finals next week which have moved from London to Turin this year, they are up to 11th in the race ahead of their final tournament of the year the Stockholm Open this coming week where they are the second seeds.