Defending champions and world record holders Australia were second fastest in 4:08:468. Russia and Ukraine will do battle for the bronze.
The three-pronged Australian women's team, which includes two members of last year's world champion combination, were fastest in qualifying for the 3000m team pursuit in 3:29:509.
The trio of Tasmania's Georgia Baker, Taylah Jennings from Queensland, and Western Australia's Kelsey Robson were more than a second faster than New Zealand, to set up another trans-tasman final tonight.
The New Zealand team of Cassie Cameron from Wanganui, Otago's Alysha Keith and Racquel Sheath from Auckland set the second fastest time of 3:30:719.
"We wanted to get off with a good start and set the right tone so hopefully tonight we can get the right colour, but it's great to be guaranteed two medals already on day one," said Machejefski.
Great Britain, who set the pace until they were pipped by just 0.1 second by the kiwis, will meet Russia for bronze medal.
Also on tonight's programme is the men's and women's team sprint.
Results, qualifying: Women's 3000m team pursuit: Australia 3:29.509, 1; New Zealand 3:30.719, 2; Great Britain 3:30.841, 3; Russia 3:34.662, 4; Mexico 3:52.356, 4.
Men's 4000m team pursuit: New Zealand 4:08.125,1; Australia 4:08.468, 2; Russia 4:09.132, 3; Ukraine 4:16.025, 4; Japan 4:16.248, 5; Belgium 4:17.316, 6; Belarus 4:18.099, 7; Switzerland 4:20.675, 8; Mexico 4:23.036, 9; Kazakhstan 4:23.732, 10; South Africa 4:25.169, 11.