It comes after James, 37, revealed Kanye West had turned down the chance twice to appear on the show and that he is currently doing everything he can to secure Beyoncé.
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On the Famous rapper bailing on him, he said: "Kanye has been booked to do [it] twice now but both times something came up. "He'll do it eventually... He wants to do it."
And on his plans to get the Hold Up hitmaker on board, he said: "It would break the internet. She's on tour right now. We're working on it."
Britney dropped the first single Make Me on 15 July, and it debuted at number 17 on the US Billboard Hot 100 chart, becoming her 34th Hot 100 entry and her sixth-highest charting debut tying with her first ever track ...Baby One More Time released back in 1998.
She has repeatedly teased that several of the tunes on the album have a "new" sound for her.
- Bang! Showbiz