The toxin cannot be removed, even if cooked or soaked.
Dr Summerell says people who eat the mushroom often experience symptoms similar to food poisoning - including nausea, diarrhoea and vomiting - between six and 16 hours after ingesting them.
"The patients appear to recover after that event, and then a few days later they'll go again into that nausea and vomiting syndrome, plus jaundice.
"Quite often, as it sounds like in this case, the end result can be death - hence the name of the mushroom - or a need to do a liver transplant."
Dr Summerell says many people are oblivious to the fact that mushrooms might be poisonous, particularly death caps which can be mistaken for straw mushrooms - common in Asian cuisine.
Death cap mushrooms were introduced in Australia during the early days of colonisation and usually grow around oak trees.
They are generally found in southern parts of the country, most notably in Canberra, Melbourne and the Adelaide Hills region.
-AAP