Dawson said he and his partner decided that they didn't have a moment to lose before marrying.
"We don't know how long we've got in the sense that the High Court might overrule the laws next week, so we thought: 'let's do it straight away and let's have the maximum amount of time being married'," Dawson said Friday from his home in the west coast city of Perth.
Canberra's iconic Telstra Tower will be illuminated with sequential rainbow colors at midnight to mark the first same-sex weddings.
The tower will provide a colorful backdrop for Alan Wright's ceremony when he weds his 30-year-old partner Joel Player.
Wright said they were fulfilling a commitment made by their celebrant Sharyn Gunn that they would be the first gay couple she would marry if it ever became legal to do so.
"Joel and I recognize everybody getting married this weekend as being the first couples to get married," said Wright, a 34-year-old civil servant.
Sydney University constitutional lawyer Anne Twomey said there was diverse range of potential outcomes to the court challenge. It could rule that no state or territory could legislate for gay marriage, or that the ACT alone could create same sex-marriage.
If the court ruled that the law can survive with amendments, Twomey could not say whether the marriages this weekend would be legal, or if the couples would have to marry again after the legislation was amended.
The advocacy group Australian Marriage Equality said at least 20 same-sex couples are marrying in Canberra this weekend.
Gay marriage has legal recognition in 18 countries as well as 16 U.S. states plus the District of Columbia.