Jordan's family called police Monday after he had been missing for a few hours. Officers searched a 20-block radius around the home, and a helicopter crew scanned open space and ponds in the area.
Montoya said on Wednesday that some investigators had worked 48 hours straight on the case.
"The emotional drain is very intense," he said. "I felt it myself, and I know the investigators felt it."
Montoya, who described the family as "cooperative to a point," declined to say if investigators are looking for additional suspects.
KCNC-TV in Denver reported that Jordan's mother attended a vigil at her son's elementary school Wednesday night. She thanked the community for helping in the search and asked for prayers, saying through tears that her son is "in a better place."
Jordan's former teacher, one of more than 200 people who gathered at Marie L. Greenwood Academy, said the boy's smile spread joy.
"Seeing him happy made me happy," said Desirae Chamberlin. "His little giggle was contagious ... He was sweet. He would pick me dandelions."
- AP