Residents of Baan Baa, Willala and Goolhi were told their lives were at risk and it was too late to leave, and they should seek shelter and avoid being caught in the open in the path of the fire.
Evacuation centres have been set up at Narrabri and Gunnedah.
Smoke from the fire on Monday could be seen across an area spanning hundreds of kilometres including Tamworth, Walcha, Armidale and even coastal communities near Port Macquarie.
There were 63 fires burning across NSW on Tuesday morning, including 15 that were yet to be contained.
More than 450 firefighters and other personnel were working to control the blazes in easing conditions for the north of the state.
No total fire bans applied, but a high fire danger rating was in place for an area stretching from Sydney west to the Victorian border.
Temperatures in the mid-30s or above were forecast for Sydney, parts of the mid-north coast, and northwest and central-west slopes and plains.