Missing world number 76 Viktor Troicki over a doping ban, Serbia captain Bogdan Obradovic will also have doubles specialists Ilija Bozoljac and Nenad Zimonjic to hand.
The fourth name remains unknown as Tipsarevic attended Wednesday's press conference alongside 117th-ranked Dusan Lajovic and lower-ranked Filip Krajinovic and Boris Pashanski.
The Czechs, playing their third Davis Cup final in five years, lifted the trophy last year after beating Spain in Prague.
They defeated Argentina 3-2 in this year's semifinals - their eighth straight Davis Cup victory - while Serbia saw off Canada by the same score in Belgrade.
The team relies on the chemistry between world number seven Tomas Berdych and 44th-ranked Radek Stepanek.
It also includes 47th-ranked Lukas Rosol and 104th-ranked Jan Hajek.
Berdych and Stepanek teamed up in 2007 and have since won 13 of their 14 Davis Cup doubles rubbers together.
The Czech Republic and Serbia last clashed in the 2012 quarter-finals, which the Czechs won 4-1 in Prague.
- AAP