Hogarty said the third student's injuries were not as severe.
Hogarty said parents had been contacted and school staff had accompanied the students to hospital.
Counties Manukau police Sergeant Ollie Nation said police received a report of a butane canister exploding at De La Salle College about 11.50am.
St John paramedics assessed eight students and teachers at the scene.
Seven people have been taken to Middlemore Hospital, five of whom were students.
It is understood classes at the school are continuing as usual for the afternoon.
The ambulance service received the callout at 11.33am and four ambulances and two vehicles are attending the incident.
Fire and Emergency New Zealand are also in attendance, a spokesman said.
De La Salle College is an integrated Catholic secondary boys' school was established in 1953 by the De La Salle brothers.