The Saudis and their Sunni Muslim allies would also be intent on preventing any vacuum being filled by the Bashar al-Assad regime, or its Shia Iranian allies, against whom the Gulf is facing off across the region.
That raises the prospect of the West being drawn directly into the confrontation between the two rival sectarian blocs.
Saudi Arabia's powerful new deputy crown prince, Prince Mohammed bin Salman, unveiled the coalition in the capital Riyadh.
"There are discussions, countries that are currently part of the coalition [like] Saudi Arabia, the Emirates, Qatar and Bahrain, about sending some special forces into Syria, and those discussions are ongoing," said Adel al-Jubeir, the Saudi Foreign Minister.
The Gulf states, some of which have been accused of supporting militants, are attempting to prove their loyalty to Western allies and their determination to take on Isis.
Jubeir said the new alliance would share information and train, equip and provide troops.
A 16-month bombing campaign has failed to crush Isis and military planners say victory will require a unified ground force that can hold territory and progress under cover of air strikes.