Authorities warned people with respiratory conditions, or heart and lung problems, to stay indoors. Office workers were seen wearing face masks in the street, an unusual sight in a city more used to clear blue skies and clean air.
Temperatures are forecast to soar to 107.6 degrees Fahrenheit (42 degrees Celsius) in the city's west. Rural Fire Service Commissioner Shane Fitzsimmons, who is leading efforts to tackle more than 80 blazes across the state of New South Wales, said it would be a "very complex, very difficult day" for his team.
Some 6.7 million acres (2.7 million hectares) of land, with a perimeter of 19,235 kilometers, have burned so far this bushfire season.
The ferocious and early start to the fires this year has stoked a debate around whether Australia's government -- a champion of the coal industry -- is doing enough to curb greenhouse gas emissions. Prime Minister Scott Morrison has repeatedly shut down claims that his government's approach to climate change has contributed in any material way to the current bushfire emergency.
The devastating fire conditions were referenced several times at an energy summit in Sydney on Tuesday, where Matt Kean, the NSW state minister for the environment, said a transition to clean energy was inevitable.
"Let's call it for what it is: these bushfires have been caused by extreme weather events, high temperatures, the worst drought in living memory -- the exact type of events scientists have been warning us about for decades that would have been caused by climate change," said Kean.
The wildfires have generated more hotspots in the past two days than any other country, according to NASA satellite data.