"All parts of this mushroom are poisonous, and eating just one mushroom can be fatal," Canberra Hospital emergency department director Dr Michael Hall said.
The poison attacks the liver - at times requiring a transplant - and unless victims can get to hospital fast enough for doctors to flush the toxin out and attack it with drugs, they can die from liver failure.
Death caps are an annual threat to the nation's capital, usually in warm, wet autumns but thriving now because of heavy summer rains.
Signs are posted throughout Canberra warning against collecting wild mushrooms because death caps, which have white gills, are similar in appearance to edible Chinese varieties.
"People should not eat any mushroom unless they can be absolutely certain that it is not poisonous," Hall said.