It will be accompanied by winds reaching 128km/h on the west coast and up to 80km/h inland which could cause further travel chaos and inflict more damage on electricity networks.
The warning comes after 50,000 homes were left without power on Christmas Day, principally in the southeast, while 150 homes in areas including Sussex and Kent were evacuated because of flooding.
An estimated 24,000 homes were still without power yesterday but many were reconnected during the course of the day.
The Met Office said the next round of stormy weather would have the potential to fell trees, cause power outages and disrupt transport networks, particularly in southern areas which were hit badly on Monday and are "sensitive" to a further onslaught.
An Environment Agency spokeswoman, speaking on Sky News, said the biggest threat was in areas around rivers which are still swelling because of rain including the Severn, Thames and Medway.
Emergency services rescued 76 people from a flooded caravan park in Yalding, Kent on Christmas Eve while more evacuations occurred in Tonbridge.