The second match will feature Kiwi No1 Rubin Statham (345th in the world) against Indian No2 Yuki Bhambri (151st), with Statham hoping his commitment to Davis Cup play can bridge a disparity in the rankings.
The doubles will see the predicted teams of Artem Sitak (43rd in the world) and Marcus Daniell (66th) against Rohan Bopana (10th) and Saketh Myneni (171st).
Doubles has been a key to New Zealand's recent success but, with Bopana having reached the semifinals at Wimbledon, the match will provide plenty of intrigue.
With the reverse singles set Sunday and the tie expected to last into the final day, Kiwi captain Alistair Hunt said his side were up for the challenge. "The boys are raring to go," he said.
"They all know each other well and both teams know there's only going to be a few points in it.
"We're expecting some really good competition this weekend with a good reward for the winner," said Hunt.
That reward will be a September encounter with one of either the United States, Croatia, Czech Republic, Germany, Italy, Japan, Switzerland or Brazil, with a crack at a place in the 2016 World Group on the line for the New Zealanders.