Also Monday, eighth-seeded Jelena Jankovic rallied for a 1-6, 6-4, 6-0 win over Anastasia Pavlyuchenkova of Russia.
Former No. 1-ranked Jankovic had lost three of her four previous matches against Pavlyuchenkova and didn't start well in Beijing, but recovered to break her opponent three times in each of the second and third sets.
The 28-year-old Jankovic, who won the title here in 2008, took control of the match as her opponent struggled with her first serves and double-faulted nine times.
Jankovic's compatriots Ana Ivanovic and Bojana Jovanovski joined her in the second round with easier straight-set victories.
Ivanovic defeated Flavia Pennetta of Italy 7-6 (9), 6-1 while Jovanovski took just 77 minutes to dispose of Sorana Cirstea of Romania 6-3, 6-2.
In the doubles, wild-card entries Serena and Venus Williams wasted chances to win before losing 6-7 (3), 6-4, 11-9 in a Champions tiebreaker to Liezel Huber and Taiwan's Chan Hao-ching. Serena Williams double-faulted on match point to hand her opponents the win, and then angrily slammed her racket against the court three times before tossing it to the side.
In the men's draw, Australian Lleyton Hewitt knocked out seventh-seeded Tommy Haas of Germany 7-6 (6), 6-3 in the first round.
Australia's Bernard Tomic, Fabio Fognini of Italy and Philipp Kohlschreiber of Germany also advanced.