Seven of the Kiwis squad played there against Wales in 2011 but it was a game watched by about only 20,000 people, not the more than 70,000 expected for tomorrow's match.
"We know we can get a lot better and I think playing at Wembley will get a lot more out of everyone," England back-rower Sean O'Loughlin said this week.
New Zealand, however, don't think the Wembley factor will play much of a role.
"I think this Wembley is a little different to the old one," said manager Tony Iro, who played in two Challenge Cup finals at Wembley in the 1980s.
"This Wembley, to me, feels like the Olympic stadium [in Sydney]. It will build its own history but at the moment it feels like another big stadium.
"A lot of boys played in the NRL finals series or grand final this year so I don't think that's going to be too much of a challenge. They are now used to playing in big, full stadiums and just get on with it ..."
Fullback Kevin Locke agrees but will also look to soak it in. The 24-year-old, who has won the battle for the fullback's position ahead of Josh Hoffman, played at Wembley in 2011 but knows it will be different playing the home side in front of a partisan crowd in a World Cup semifinal.
"We know this is big for England and they will come out with a bang," he said. "We will be doing the same because we know we have the support back home. Being part of the Kiwis ... is something special."