The U.S. won its final five games at the World Curling Federation's qualification event in the Bavarian town of Fuessen, and the Shuster rink will now be nominated to the U.S. Olympic team pending approval by the United States Olympic Committee.
"The butterflies of winning for an opportunity like this, they never get old. That's why we play this game," said Shuster, who won Olympic bronze in 2006 in the lead position.
"These guys work their tails off and they're some of the best in the business. I'm extremely proud of how well our team has played the entire season and especially here when we had our backs against the wall," the 31-year-old Shuster said.
Jiri Snitil's Czech rink was playing its second playoff in as many days after losing to Germany for the first Olympic berth on Saturday.
China and Japan both qualified for the women's tournament in Sochi next year by winning their decisive playoffs on Sunday.
China beat Japan 7-6 in the playoff between the first and second-ranked teams, and Japan later qualified with a 10-4 victory over third-place Norway.