Singers Adele, Sir Paul McCartney, Sir Elton John, Mick Jagger and Kate Bush are also expected to step up to the microphone, while 4000 ordinary Brits will play a part.
Closing ceremony music director David Arnold, whose credits include half a dozen Bond films, described the event to media as the "greatest after-party in the world".
Te Awamutu-raised expat dancer Ian Vincent will perform as part of the cast of the hit show Stomp.
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New Zealand Olympic Committee spokeswoman Ashley Abbott confirmed most Kiwi athletes would be on two flights arriving in Auckland on Wednesday morning.
A few Olympians have chosen to take well-deserved holidays after the Games, with equestrian Mark Todd booked in for a family skiing holiday.
Kiwi swimmer Natalie Wiegersma will continue her break from the tiny Southland hamlet of Dacre with a week visiting family in the Netherlands;
rising swim star Lauren Boyle, who finished an impressive fourth in the women's 800m freestyle, is heading to Germany to see an old school friend; and another swimmer, Dylan Dunlop-Barrett, is off to Poland.