Earlier, Kiwi spinner Leigh Kasperek's four-wicket haul helped New Zealand bowl out the West Indies for just 194 in the 49th over.
Medium pacer Lea Tahuhu, who finished with figures of 3-42, snared the wicket of opener Hayley Matthews in the fifth over and also took the last wicket of the innings when she removed skipper Stafanie Taylor for 86.
Taylor's 54-run third wicket stand with Chedean Nation (35) aside, the Windies struggled to build partnerships of substance.
The New Zealand bowlers kept the visitors well under wraps, Kasperek leading the way with 4-44, with support from Devine and Anna Peterson.
New Zealand are now 2-0 up in the five-ODI series.
-NZN