The incident happened just before 5pm on November 2, 2012, at Tasman Tanning's plant.
Two workers were flown to Wellington Hospital in a critical but stable condition after a mix-up with chemicals created a cloud of hydrogen sulphide.
Another 19 people exposed to the gas were assessed at Wanganui Hospital.
The two seriously injured men were released from hospital about a week later.
Mr Tait later said the incident would have to be put down to operator error.
"Sulphuric acid was added to the wrong processor at the plant and the combination with the chemicals in that processor caused the hydrogen sulphide cloud," he said.
Mr Tait said the two injured workers were "very good, long-standing employees with excellent work records". "We all make mistakes, but all these procedures we have are being investigated by the appropriate government people."
Mr Tait said all staff were kept up to date about handling chemicals and it was something the company regularly revisited.