However, after a series of successful mediation meetings, the company pulled out and the union resumed its industrial action, he said.
"That was met with our members coming in to work today and being told to go home and being told that they were suspended without pay 10 days out from Christmas."
The union members were not forewarned of the suspension, Mr Goldman said.
"The first we knew of it was when our members turned up to work and they were told not to be there."
The company's actions appeared to be in accordance with the Employment Relations Act, he said.
Mr Goldman said they hoped to return to the bargaining table with the company.
"We're hopeful that they'll agree to that," he said.
"We're putting in an application today to the Employment Relations Authority for urgent facilitated bargaining."
Anglican Family Care provides caregiver support, home visits by social workers, and food bank and budgeting services for vulnerable Otago families.
The affected staff members represented just over half of the company's employees.
PSA national secretary Richard Wagstaff described the company's actions as "an extremely aggressive step to take, especially just before Christmas".
Anglican Care director Nicola Taylor declined to comment on the industrial action or the union members' suspension.