"This will be treated very seriously. Investigation will follow and hopefully lead to the prosecution of the person who did this.
"We take a zero tolerance on people wasting emergency services and resources.''
There had been no contact from whoever was responsible but police had "a few'' leads to follow up.
The man who opened the envelope spilled some on his hands and had to be decontaminated by the Fire Services, as did a firefighter.
The Whitcoulls employee was speaking to counsellors following the experience.
"Obviously opening an envelope with a substance unknown to you is going to be uncomfortable for anyone and it's going to play on their emotions,'' Mr Clifford said.
"It's just lucky we were able to do an examination here at the scene to determine what the powder was and give a bit of comfort and ease to that person to know they're no longer at risk.''
Fire Service senior station officer John Mansford said the large emergency services turnout was needed in case the situation was major.
Whitcoulls remained open during the incident.