A snow warning has been issued for the Rimutaka ranges in Wellington.
Drivers have been urged to take care after MetService issued the warning.
Snow showers were expected throughout the day, with the possibility of 4cm to 6cm accumulating.
The New Zealand Transport Agency is warning motorists to drive with caution.
• -20 degrees recorded at Pukaki, close to the country's coldest ever recorded of -25.6 in Ranfurly in 1903 • -5 degrees in Dunedin, Blenheim and Taumarunui • -2 degrees in Hamilton • 2.7 degrees in Auckland
New Zealand has nearly shuddered itself to the MetService's record books after Mackenzie Country plummetedto -20 degrees overnight.
MetService Meteorologist Stephen Glassy said most of the South Island recorded sub-zero temperatures including the -20 at the Pukaki Aerodrome on the edge of Lake Pukaki.
Lake Tekapo and Mt Cook Airport got down to -13 degrees, while Queenstown, Alexandra and Lumsden hit -7 degrees.
Auckland International Airport was 2.7 degrees while Ardmore Airport was currently sitting at 1.5 degrees.
Meanwhile, Canterbury Police have issued a black ice warning and urging motorists to take extreme care this morning.
Cars struggle for traction on the ice in Wakari Rd. Photo / Gerard O'Brien, ODT
Senior Sergeant Richard Ryan said the condition of the district's roads were "treacherous as the overnight rain has now frozen".
"Police have attended a couple of minor accidents already today that can be attributed to the black ice which has set on the roads. Road contractors are being utilised to try and alleviate the current problem."
Police ask motorists to allow extra time for travel today, to drive to the conditions and be mindful that black ice is often very difficult to see.
A dog named Bear enjoys the snow at Whare Flat yesterday. Photos / Peter McIntosh, ODT
In Christchurch, University of Canterbury exams have been pushed back an hour due to the big freeze.
"Due to icy road conditions in Christchurch a decision has been made to delay the start of morning examinations until 10am," a campus spokesperson said via the university's Facebook page.
"Afternoon examinations will go ahead as scheduled. Students are urged to take care travelling to and from university."