The two erectile dysfunction treatments are promoted and sold in New Zealand by various retailers, including "adult" shops, and over the internet.
They are advertised as a way to enhance sexual performance or treat erectile dysfunction.
Tests completed by the Institute of Environmental Science and Research found both contained significant quantities of prescription drugs.
Get Stiff contained vardenafil, which can interfere with heart medications and can be harmful and even fatal if misused, the Ministry of Health said.
Maxi Mize contained hydroxyhomosildenafil and hydroxythiohomosildenafil, which have not been tested and approved as safe for use in New Zealand.
Mr Woods said Medsafe had found prescription medicines in 65 herbal supplements aimed at enhancing sexual performance since 2009.
"I advise consumers to treat with extreme caution products purportedly for the treatment of erectile dysfunction or to improve sexual performance offered for sale without a prescription. They should seek medical advice before using them."
Sponsors, distributors, retailers and importers are required to be aware of all the active ingredients contained in their products under the Medicines Act 1981.