"Since when did smoking becone (sic) a fashion statement? im definatly (sic) not impressed," Harriet Stephens added.
Smoking has a long history with the fashion industry, representing the epitome of cool and glamor in the 50s, but the practice is now seen as outdated.
"That girl is filling herself with poison...over 7000 different chemicals. Grow up Dior this is 2016," Madison McCollough wrote.
"Ahhhhhh @dior you dropped the ball here ... you know how many people die from smoking? Not good," Stephanie Ainsworth added.
Dior responded immediately to the rash of criticism, removing the photo from its Instagram account.
The controversial pic also appears to be absent from the Dior website, which is overtaken by the Poison campaign.
- AAP