"My little brother was in Australia and sent a tape across. He got a callback, got another callback, and was down to the last four or five people in it," said Hemsworth.
The beefy star was in Canada filming the horror hit Cabin in the Woods when news trickled through that none of those last few actors were deemed suitable for the role - his brother included.
"My manager called [them] up and said 'You know [Liam's] got an older brother, could we bring him back in?'"
He filmed another audition in Vancouver with his mum reading co-star Anthony Hopkins' lines.
"She must have nailed it, because it got me back in the room.
"That second audition was a lot different to the first one. I came in with a lot of motivation, and maybe frustration, that my little brother had gotten further than me. Sibling rivalry kicked up in me, and it moved pretty quickly from there."
The rest, as they say, is history - Hemsworth is currently filming what will be his ninth big-screen appearance as Thor in the Marvel cinematic universe, while T hor: Ragnarok is set for release just next month.