During a hearing at the Manhattan Supreme Court, De Niro's lawyer Caroline Krauss-Browne said that the prenup is clear about what Miss Hightower is entitled to. She accused Miss Hightower of chasing her client for every single cent she can get.
Miss Krauss-Browne said: "She is seeking essentially every piece of paper of De Niro's receipts for meals on movie sets, wardrobe, payroll records of every employee... credit card charges. This all goes back 15 years."
Miss Hightower's lawyer Allan Mantel said the couple's revenue since the prenup was signed is around $449m, out of which $374m came from films. The majority of the rest came from his stake in the Nobu sushi chain.
He said Miss Hightower, an actress, earned just $23,000 a year and wanted to be treated equally.
Justice Matthew Cooper said he was considering sending them to mediation, adding: "We are talking millions of dollars here."
The couple split last December and are also fighting for custody of their seven-year-old daughter Helen Grace, who was born via a surrogate. They also have a 21-year-old son, Elliot.
Neither De Niro nor Miss Hightower commented as they left court. The hearing continues.,