Slick's thundering contralto, dubbed "the voice that launched a thousand trips", would define the Airplane's sound in anthems such as White Rabbit and Somebody to Love.
The group performed at Woodstock and two other hippie gatherings of the era, Monterey and Altamont. Balin was knocked unconscious at Altamont while trying to stop the Hell's Angels security guards "beating this guy with pool cues", as he recalled. "When I woke up I had all these boot marks tattooed all over me."
Balin left the group in 1971, later blaming cocaine: "I personally just drank alcohol. But some of the chemicals made people crazy and very selfish, and it just wasn't any fun to be around for me."
He formed the short-lived Bodacious DF, then in 1975 rejoined his old band. The lineup was changed but still led by Slick and Kantner, and renamed Jefferson Starship.
Balin left again in 1978 after the band's sound had become pop-tinged, bland and corporate.
He continued recording and in the early 1980s enjoyed several US hit singles.
Balin was born Martyn Jerel Buchwald in Cincinnati, Ohio, on January 30, 1942.
He is survived by his third wife, Susan Joy Balin and two daughters.
- Telegraph Media Group