Kardashian tied the knot with the former New Jersey Nets player in August 2011 after 10 months of dating, but then filed for divorce just 72 days later, citing irreconcilable differences.
Kim and Kanye began dating six months later in April, 2012, and they married in Italy in May 2014, less than a year after the reality TV star gave birth to their first child, daughter North West, in June, 2013.
The couple welcomed second child, son Saint, in December last year.
Kardashian, who appeared on the show alongside West and fellow guests John Legend and Chrissy Teigen, revealed she was no longer breastfeeding Saint because North West was jealous.
"She would cry so much and try to pull him off me. She was so jealous she took her little milk box and put it in my bra with the straw sticking out and she wanted to drink while he was drinking," Kardashian said.
North West has since had a change of heart.
"This week she goes to me, "Mommy I'm not mad anymore, you can feed baby brother I won't cry'," she said, "and I was like, "Look honey, the milk is all dried up'," Kardashian said.
- AAP