The couple are just the latest in a long list of stars who have invested in wine from ex-Formula One champion Michael Schumacher, singer Sting and footballer David Beckham to actor Gerard Depardieu, filmmaker Francis Ford Coppola, singer Madonna and Tool frontman Maynard Keenan.
The website mesvignes.com says the majority of celebrity vineyard owners are not actively involved in the process.
Jolie and Pitt, however, want to do more than "just put their name" on the bottle, according to Marc Perrin.
"They want to be proud of the wine on their property. They are really looking for excellence," he said.
"We are two families at the service of the estate."
Perrin said he expected there to be around 150,000 bottles of the rose wine on the market in the first year, followed later by red and white wine.
The wines would be sold through "good wine merchants and in good restaurants", he added.
- AFP