A SFO spokeswoman said the Roses, both 42, were husband and wife - at least at the time of alleged offending.
MRP chief financial officer William Meek said the charges relate to a historic matter and that any financial impact was absorbed into past accounts.
The company has changed its procurement and inventory management process to minimise the "risk of recurrence".
Any decisions around recovery options would be made by the company following the SFO's court action, Meek said.
The alleged offending came to light following a investigation by MRP, which referred the matter to the police. It was subsequently referred to the SFO, which began an investigation in April 2013.
"This investigation resulted from observations and internal checks at Mighty River Power. The company's actions in referring this matter to the Police and the active support for the SFO's investigation means that we are now in a position to lay charges and prosecute the people involved, " SFO director Julie Read said today.
The defendants will next appear in the Auckland District Court on September 30.