The council measure these through particulate matter (PM10), with an exceedance being any reading above 50 micrograms per cubic metre averaged over 24 hours - the council's site at St Johns recorded an average level of 55 micrograms to midnight Monday.
Weather conditions meant smoke levels in the air rose steadily from Sunday morning.
After last month's milestone, Dr Kozyniak had said there was an overall improving trend, and in terms of health any winter month without an exceedance "is a win for Napier and Hastings residents".
Napier has not had an exceedance of the air quality standards for two years. The city may only exceed the limit once a year, while Hastings can exceed no more than three times, before reducing to only one exceedance a year by September 2020.
Before the council's HeatSmart programme began in 2009, there was a high number of annual exceedances, particularly in Hastings and to a lesser degree in Napier.
The programme was set up to improve air quality in Hawke's Bay by reducing air pollution from home wood-burners and fires because of the adverse effects on people's health.
Since it started more than 9500 fireplaces had been upgraded or replaced, with insulation retrofits and upgrades in many homes.
Open fires inside households in Napier and Hastings air sheds were outlawed in 2012 and use of non-compliant wood-burners will be prohibited from next January for Hastings and from January 2020 for Napier.