The pair, who separated almost a decade ago after 17 years of marriage, have already been through the Family Court, High Court and Court of Appeal.
Now the case is going to the Supreme Court after applications for leave to appeal were granted today.
The decision now being challenged redrew "the landscape" on trusts and relationship property, according to one lawyer on the case.
Earlier this year the Queen's Counsel for Melanie Clayton, Lady Deborah Chambers, said that was because the Court of Appeal found powers of appointment for trusts are property.
LeeSalmonLong partner Isaac Hikaka also said at the time the decision was the first with such a clear statement that this is a particular power that is an item of relationship property and that it has a specific value.
"So it's likely to have widespread effect not just on relationship property law but also the way in which trusts are framed going forward," Mr Hikaka said in March.
The questions that will be considered by the nation's highest court include whether powers under the trust deed in question are property and if so, did the Court of Appeal made an error in valuing that power.