She also reached 37m in the constant weight (CWT) with monofins and 33m for CWT with no fins.
The CWT depths were both personal bests, Rounthwaite's no-fin effort eclipsing her 21m of the year before.
"It was quite a big jump, and it felt like it," she said.
"I was looking at the rope and wanted to grab it, which would have given me penalties.
"I was knackered after that one, I was shattered."
Rounthwaite trains at holding her breath at the Wanganui Splash Centre, but does have access to deep water facilities in her home town so she cannot train with the 3.5-4kg weights the competitors wear in CWT events.
She attended a three-day camp at the lake before the nationals and managed to set a 37.9m personal best in FMI.
"It's a lot of fun, free immersion's cool, there's something very rhythmic about it," Rounthwaite said.