The vats had boiled over on numerous occasions in the past, resulting in burns to another worker on one occasion, the summary said.
The investigation also found the liquid entered the worker's boots because the worker was not provided with adequate personal protective equipment, and the worker had not been given proper supervision or training.
WorkSafe head of specialist interventions Simon Humphries said the company should have known better.
"These vats had reached boiling point on many occasions, putting workers at risk of serious harm," he said. "Our investigation found workers were simply told to avoid vats when they boiled over. Heinz Wattie's should have had effective controls in place to eliminate the known risk to its workers."
He said that if companies became aware of a safety problem they were required to fix.
"They didn't," he said, "and that is simply not acceptable."