Mr Pakato expressed condolences to Mr Boucher's family, saying "may God comfort them in this difficult time for all of us".
Since the pair arrived in New Zealand, with Mr Pakato's fiancee, they had uploaded videos of them sightseeing in Auckland, Tauranga, Rotorua and other locations.
Police were still investigating the cause of the crash, but Senior Sergeant Ian Campion confirmed a large object fell from a truck into the path of the young man's car.
A portable toilet can be seen on the roadside in the accompanying aerial photograph of the scene.
"He had to take evasive action, swerving to the left to avoid colliding with the object," Mr Campion said.
"In doing so it appears he lost control of the vehicle, veered back across the road and collided with a truck and trailer unit travelling in the opposite direction."
The 49-tonne truck and trailer unit rolled off the northbound lane of the highway and came to rest upside down with the driver still inside.
Mr Campion said police were liaising with Mr Boucher's family through the French Embassy.
The driver of the truck that Mr Boucher collided with was unhurt, but badly shaken. He was driving for Auckland-based company Jackson Road Haul.
Owner Scott Jackson said the man, in his 50s, had worked for the company for 20 years and was highly experienced.
The driver was heading to Thames to drop off a load of sawdust at a mill after loading in Kawerau when the crash happened, he said.
Mr Jackson said the driver managed to get out of the truck, possibly with the help of people at the scene.
"He is as well as can be expected but naturally he is still badly shaken up. This was the first time he has ever been involved in anything like this."
The truck suffered major damage and was impounded at Rowe Motors.
Mr Jackson said his thoughts were with the victim's family. "The accident is clearly no-one's fault. It's an absolute tragedy." Additional reporting by Sandra Conchie